It's a win3.1 game. It *should* run on XP (you may have to right click the exe and set it to Win95 compatibility mode, however)
For running it on XP Home / XP Pro, there's no difference. the kernels of both are exactly the same (pro just has more network-admin type of crap in it)
Btw Baikon.. it's a joke getting most good DOS games to run on XP.. what you gotta do is make a dos bootdisk with CD, mouse, and sound and boot directly to dos, and run the game.